Grain refinement of magnesium alloy az91e ubc library. This process is experimental and the keywords may be updated as the learning algorithm improves. The almgzn system has a relatively complex equilibrium diagram. A ternary phase diagram for mg alloys with al and zn additions is shown in figure 2. Alloying capacity for the solid solution of alloys. The effects of different zn contents on the microstructure and mechanical properties were systematically investigated. He also detected the first ternary phase, having a large homogeneity. The only condition for the applicability of phase diagrams as a powerful tool in materials. Thermodynamic properties prediction of mgalzn melts. Zhang, phase equilibria and thermodynamics of the mgsili system and remodeling of the mgsi system, j.
Two software packages, bingssbinfkt 77luk, 92luk and thermocalc. It is consistently found that the composition of this phase is close to mg49. Types, compositions, and fractions of phases are given by the equilibrium. Thermochemical analysis of phases formed at the interface of a mg alloyniplated steel joint during laser brazing. All the commercial mg alloys like az, am, ae, ez, zk, and so forth series are multicomponent and hence it is important to understand the phase relations of the alloying elements with mg. While typical mgalzn casting alloys such as az91 are alrich. Thermodynamic modelling of mnsn and mnsr binary systems is carried out using the reliable data from the literature. Table 1 thermodynamic models of the binary or ternary phases in mgalzn system11 phase type thermodynamic model l solution mg, al, zn. As can be seen from the phase diagram, az alloys may contain mgzn and mgal solid solutions, as well as mgalzn phases. Tcmg is a thermodynamic database for mgbased alloys for use with the thermocalc software package. Computationalstudy of atomicmobility in hcpmg al zn. The calculated phase diagrams and the thermodynamic properties are found to be in good agreement with the experimental data from the literature. This repository provides a source for interatomic potentials force fields, related files, and evaluation tools to help researchers obtain interatomic models and judge their quality and applicability. The recent discovery of c36 phase in the ascast samples of gm.
Materials free fulltext effect of zn content on the. The al solute does not diffuse completely in the melt, and builds up the soluterich layer in front of the solidification interface, resulting in the decline of the solidification temperature of the melt. Investigation in mgalcasrzn system by computational. Calphad calculation of phase diagram by liang et al. Phase diagram calculations are an important topic in material science. Each point inside that prism is a fixed state point with unique constitution. Thermochemical analysis of phases formed at the interface. Phase diagrams and properties of different phases can be. Thermodynamic calculations of the mnsn, mnsr and mgmn. For the systemsthat have been considerably or significantly improved, the phase diagrams are recalculated with tcmg4.
The quaternary system alcumgzn is one of the key systems of highstrength. The first one plots the gibbs free energy versus composition for alzn, limg, and peltons. The addition effect of ca, sr, and zn on am50 alloy is discussed and the available experimental observations in mgalca, mgalsr, and mgalzn alloys were successfully explained. More detailed calculation shows that 15% ce is required to completely suppress the formation of the mg. The phase diagrams of the mgal, mgzn and alzn systems calculated by the thermocalc software are shown in fig. The thermal cycle of fusion welding processes results in liquation and formation of. Essential magnesium alloys binary phase diagrams and their. Introduction calcium and strontium are important components in.
Computational study of atomic mobility in hcp mgalzn. According to the quaternary phase diagrams alfecumg, alfemgmn, and. One may envisage the complete ternary mgalzn phase diagram at constant pressure as a prismatic 3d model, spanned by the triangular composition base and a vertical temperature axis. In the automotive and aviation fields, the complex use environment is critical to the performance requirements of materials, the corrosion resistance of materials severely limits the service life o. Examples of binary phase diagrams are found even for organic10 and. Liquidus and solidus temperatures of mgrich mgalmnzn. Users are encouraged to download and use interatomic potentials, with proper acknowledgement, and developers are welcome to contribute potentials for inclusion. Understanding the phase formation in mgalcasr axj alloys and modifications of mgalzn az and mgalmn am alloys with ca andor sr requires accurate.
Effect of calcium on structure, phase composition and. Ternary nanoscale precipitates have been found consistent with the predicted. The calculated phase diagrams and the thermodynamic properties are found to be in good agreement with the experimental data from. Models for multicomponent alloys are built in a methodical approach from quantitative descriptions of unary, binary and ternary subsystems. Phase diagram isothermal section intermediate phasis ternary phasis mgzn these keywords were added by machine and not by the authors.
The alloys based on the mgalzn ternary system known as az are the most widely used magnesium alloys in the automotive industry owing to their excellent castability and recyclability, low cost and relatively high strength. The addition of zn obviously refines the ascast alloys dendritic structure because of the increase in the number in the second phase. The use of stable and metastable phase diagrams and appropriate choices of state variables are explained for the relevant fec system. Bikram konar, donggeun kim and inho jung, coupled phase diagram experiments and thermodynamic optimization of the binary li 2 omgo and li 2 ocao systems and ternary li 2 omgocao system, ceramic interantional, 2017, vol. Mg dendrite precipitates first during the solidification process, and then expels the redundant al solute. The mgalznmncasr alloy system backbone of understanding phase formation in axj alloys and modifications of az and am alloys with ca or sr. Limited amount of experimental data could be found in the literature for the alcazn ternary system phase diagram of quaternary alcamgzn system is unknown. Calculated phase diagram reveals important phase details for a new type muticomponent magnesium alloy. Magnesiumbased alloys are becoming a major industrial material for structural applications because of their potential weight saving characteristics. This technology report is an introduction to software based phase diagram calculations. Essential magnesium alloys binary phase diagrams and their thermochemical data.
This paper determines the effect of pressure during crystallization on the change in content of alloying component in solid solution of alloys based on aluminum and magnesium. Key words mgalzn alloy, phase equilibrium thermodynamics, microstructure, solidi. Microstructure and properties of mgal binary alloys. Progress in systematic development of a thermodynamic database for mg alloys with 21 components is reported. A selfconsistent thermodynamic database for the mgmnsn, sr systems is constructed by combining the thermodynamic descriptions of their constituent binaries. Systematic semeds measurements for the white contrast phase have been conducted. When the alsic master alloy was added to molten az91e alloy, the al matrix melted and allowed the sic particles to distribute homogeneously throughout the molten az91e alloy. Microstructure and properties of mgzny alloy powder. Computational study of atomic mobility in hcp mgalzn ternary. Thermodynamic assessment of the alcuzn system, part iii. Experimental study and phase diagram calculation in alznmgsi quaternary system. The mgcu,zn 2 phase originates in the mgcu phase diagram and has extensive solubility of zn in the mgcuzn ternary system. Thermodynamic modeling of mgca and alca binary systems.
Mgalzn alloy with solidus and liquidus temperatures of 718 k and 873 k. Spark plasma sintering sps process has been used to develop a novel grain refiner alsic master alloy for az91e mg alloys. An introduction to applications of this approach to phase formation in ascast and heat treated mg alloys is given and discussed in detail for the example of ternary mgalzn alloys. Apdic, the alloy phase diagram international commission, coordinates worldwide activities of 17 member organizations involving 20 countries. Based on the concentration profiles from the literature, the diffusion coefficients have been reextracted using the hall method for the impurity diffusion, and the sauerfreise and the whittlegreen strategies for interdiffusion coefficients in binary and ternary. Comparisons of the modelcalculated phase diagrams and thermodynamic. Localelectrode atomprobe tomographic investigation of. Keywords calphad approach, experimental phase equilibria, invariant equilibria, liquidus surface, microstructure phase diagram 1. Microstructure and corrosion resistance of al3zr, tial. On mgalzn intermetallic alloys made by friction stir.
Download scientific diagram mgrich end of the mgal and mgalzn phase diagrams. The study was carried out on alloys of systems based on industrial alloys al. Corrosion behaviour of az31 magnesium alloy in highly. From the ternary phase diagram, it has been shown that the formation of i, w or x phase depends on the yzn ratio in mgzny alloys 26,27. For the mg 97 zn 1 y 2 alloy investigated in the present study, yzn ratio was 2 and the. Scheil cooling calculation for az31 alloy mg3al1zn0. The most useful zerophase fraction lines in phase diagram sections of multicomponent systems are made clear by coming back to the cuni and mgalzn systems. During the optimization of the thermal conductivities, the thermodynamic equilibrium information, such as solid solubility and mole fraction of phases, were simultaneously extracted by using the thermodynamic database for the mgalzn system. Computational thermodynamics and kinetics for magnesium. Modelling of phase transformations in magnesium alloys. They are usually carried out with limiteddistribution software packages. A sound thermodynamic description of the ternary mgalzn was provided via calphad calculation of phase diagram by liang et al. Sembei micrograph showing the phase dispersion in mg 70 al5zn. Taji nishizawa 1994, calphad 18, 1994, 368, in recognition of his contributions to the understanding of ternary phase diagrams, in particular the magnetic effects which he has studied by means of a unique combination of experimental and computational techniques.
Quaternary system an overview sciencedirect topics. However, due to the calculation results built on a given. Deconstructing phase diagram calculations journal of. Calc software to carry out the optimization and calculation. Almgzn phase also appear, which are hardening phases, but have a lower stability in the mgzn than mgzn 2. Note that some phase diagrams have been calculated with older versions of the tcmg database. Mgznla ternary system was experimentally investigated by dobatkina et al. The extension to truly multicomponent alloy systems and advanced kinetic calculations is briefly depicted. Thermodynamic properties of the binary liquid solutions are described using the modified quasichemical model.
Thermodynamic description of reactions between mg and cao. Dsc as well as calculation of phase diagram based on pandat software. The oxide cao2 is not stable at these temperatures. Isothermal section of the mgalzn phase diagram at 500 c. Experimental study and phase diagram calculation in alznmgsi. Calcium and strontium are important components in advanced magnesium alloys, which are relevant for weight savings in the automotive industry or other applications as detailed in part i of this study. Later, prince 23 assessed the system based on the work of kono.
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